Authorities began their investigation last week into 37-year-old Xiong Cha for possible child abuse at a home near Gettysburg and Fowler.
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All of the children were taken from the home, but Cha was not found.
Tuesday afternoon, he was spotted at his home by undercover officers. They tried arresting him at a gas station, but police say he sped off and crashed into an unmarked patrol car.
A chase followed and police used a PIT maneuver to stop Cha's car near Clovis and Jensen.
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He was taken into custody and a handgun was found in the car.
Cha was booked into the Fresno County Jail on a number of charges.
Police also arrested the mother, 37-year-old Dou Vang, for child abuse.