The man has been identified as Emad Murshed of Kerman, and the woman has been identified as Yvette Jimenez of Firebaugh.
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California Highway Patrol officers are on the scene of a fatal accident on Highway 180 near Hayes Avenue in Fresno County.
Officers say two vehicles collided head-on, and both drivers died on impact. They were the only occupants in each car.
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The crash happened around 11 p.m. It's not clear what caused the accident.
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The roadway will be closed for several hours into the night as crews investigate.